Crucible steel

Crucible steel describes a number of different techiques for making steel alloy by slowly heating and cooling iron and carbon (typically in the form of charcoal) in a crucible.

The first form of crucible steel was wootz, developed in India some time around 300 AD. In this system the iron was mixed with glass and then slowly heated and then cooled. As the mixture cooled the glass would bond to impurities in the steel and then float to the surface, leaving the steel considerably more pure. The technique slowly spread from India until it reached the Middle East about 1000 AD, where it gave rise to Damascus steel, famed throughout the world.

As early as the 17th century, Europeans knew of India's ability to make crucible steel from reports brought back by several travellers who had observed the process at several places in southern India. Several attempts were made to import the process, but failed because the exact technique remained a mystery. Studies of wootz were made in an attempt to understand it's secrets, including a major effort by the famous scientist,Michael Faraday, son of a blacksmith. Working with a local cutlery manufacturer he wrongly concluded that it was the addition of aluminium oxide and silica from the glass that gave wootz its unique properties.

Meanwhile a new crucible technique was developed in England by Benjamin Huntsman, a clockmaker in search of a better steel for clock springs. In 1740 he moved to Sheffield, and after years of experimenting in secret he perfected his process. Huntsman's system used a coke-fired furnace capable of reaching 1600°, into which ten or twelve clay pots (crucibles), each holding about 15 kg of steel, were placed. When the pots are at a white heat they are charged with blister steel broken into lumps of about ½ kg. The pots are removed after about 3 hours in the furnace, impurities skimmed off, and the molten steel poured into ingots.

Before the introduction of Huntsman's technique, steel production had been based on using the unusually pure iron from Sweden, packed into stone boxes with charcoal and heated in a furnace for an entire week. In 1740, Sheffield produced about 200 tonnes of steel per year based on this older system. The introduction of Huntsman's techniqued changed this radically, one hundred years later the amount had risen to over 80,000 tonnes per year - almost half of Europe's total production. This discovery enabled Sheffield to develop from a small township into one of Europe's leading industrial cities.

Another form of crucible steel was developed in 1837 by the Russian engineer, Pavel Anosov. His technique relied less on the heating and cooling, and more on the "quenching" process of rapidly cooling the molten steel when the right crystal structure had formed within. He called his steel bulat, but the secret died with him.

Cruicible steels remained the world's best, although very expensive. The introduction of the Bessemer process replaced it outright however, able to produce steel of similar (or better) quality for a fraction of the time and cost.