Plumbocene
| |
| Identifiers | |
|---|---|
| Properties | |
| C10H10Pb | |
| Molar mass | 337.4 g·mol−1 |
| Boiling point | 150 °C at 10−7 mmHg[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Plumbocene is an organometallic compound of lead. It is a member of the class of metallocenes. It is soluble in benzene, acetone, ether, and petroleum ether, and insoluble in water. Plumbocene is stable in cold water.[1]
Plumbocene is not commercially available. It may be synthesized by the reaction of sodium cyclopentadienide with a lead(II) source such as lead(II) nitrate[1] or lead(II) iodide.[2]
The decamethyl analog, Cp*2Pb, and the half-sandwich complexes, Cp*PbBF4 and Cp*PbCl, are known as well.[3]
References
- ^ a b c Fischer, E. O.; Grubert, H. (1956). "Über Aromatenkomplexe von Metallen. IV. Di-cyclopentadienyl-blei". Zeitschrift für anorganische und allgemeine Chemie. 286: 237. doi:10.1002/zaac.19562860507.
- ^ Izod, Keith; McFarlane, William; Wills, Corinne; Clegg, William; Harrington, Ross W. (2008). "Agostic-Type…Pb Interactions Stabilize a Dialkylplumbylene. Structure of and Bonding in [{nPr2P(BH3)}(Me3Si)C(CH2)]2Pb". Organometallics. 27: 4386. doi:10.1021/om800598b.
- ^ Jutzi, Peter; Dickbreder, Reiner; Nöth, Heinrich (1989). "Blei(II)-Verbindungen mit π-gebundenen Pentamethylcyclopentadienylliganden – Synthesen, Strukturen und Bindungsverhältnisse". Chemische Berichte. 122: 865. doi:10.1002/cber.19891220512.